Halogen isotope publications (2006-2010)

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C. Aeppli, H. Holmstrand, P. Andersson & O. Gustafsson. Direct compound-specific stable chlorine isotope analysis of organic compounds with quadrupole GC/MS using standard isotope bracketing. Analytical Chemistry 82 420-426. doi:10.1021/ac902445f

J.D. Barnes & S.M. Straub. Chlorine stable isotope variations in Izu Bonin tephra: Implications for serpentinite subduction. Chemical Geology 272 62-74. doi:10.1016/j.chemgeo.2010.02.005

T. Fujitani, K. Yamashita, M. Numata, N. Kanazawa & N. Nakamura. Measurement of chlorine stable isotopic composition by negative thermal ionization mass spectrometry using total evaporation technique. Geochemical Journal 44 241-246. Abstract

F. Gelman & L. Halicz. High precision determination of bromine isotope ratio by GC-MC-ICPMS. International Journal of Mass Spectrometry 289 167-169. doi:10.1016/j.ijms.2009.10.004

H. Holmstrand, Z. Zencak, M. Mandalakis, P. Andersson & O Gustafsson. Chlorine isotope evidence for the anthropogenic origin of tris-(4-chlorophenyl)methane. Applied Geochemistry 25 1301-1306. doi:10.1016/j.apgeochem.2010.06.001

H. Holmstrand, M. Unger, D. Carrizo, P. Andersson & O. Gustafsson. Compound-specific bromine isotope analysis of brominated diphenyl ethers using gas chromatography multiple collector/inductively coupled plasma mass spectrometry. Rapid Communications in Mass Spectrometry 24 2135-2142. doi:10.1002/rcm.4629

W.A. Jackson, J.K. Bohlke, B.H.Gu, P.B. Hatzinger & N.C. Sturchio. Isotopic Composition and Origin of Indigenous Natural Perchlorate and Co-Occurring Nitrate in the Southwestern United States. Environmental Science and Technology 44 4869-4876. doi:10.1021/es903802j

T. John, G.D. Layne, K.M. Haase & J.D. Barnes. Chlorine isotope evidence for crustal recycling into the Earth's mantle. Earth and Planetary Science Letters 298 175-182. doi:10.1016/j.epsl.2010.07.039

G. Kohler & L.I. Wassenaar. The stable isotopic composition (Cl-37/Cl-35) of dissolved chloride in rainwater. Applied Geochemistry 25 123-142. doi:10.1016/j.apgeochem.2009.10.004

M. Musashi, H.G.M. Eggenkamp & Ph. van Cappellen. 超臨界水分解による塩素抽出法の開発:塩素系環境 汚染物質中の塩素安定同位体比測定 (Experiment on chlorine extraction from chlorinated pollutants by supercritical water and their Cl isotope analysis.) 芝浦工大研究報告理工系 (Bulletin of Science and Technology Shibaura Institute of Technology) 54:57-61. PDF

V. Lavastre, C. Le Gal La Salle, J.L. Michelot, S. Giannesini, L. Benadetti, J. Lancelot, B. Lavielle, M. Massault, B. Thomas, E. Gilabert, D. BoerlŔs, N. Clauer & P. Agrinier. Establishing constraints on groundwater ages with 36Cl, 14C, 3H, and noble gases: A case study in the eastern Paris basin, France. Applied Geochemistry 25 123-142. doi:10.1016/j.apgeochem.2009.10.006

J.C. Laube, J. Kaiser, W.T. Sturges, H. B÷nisch & A. Engel. Chlorine isotope fractionation in the stratosphere. Science 329 1167. doi:10.1126/science.1191809

Z.D. Sharp, J.D. Barnes, T.P. Fischer and M. Halick. An experimental determination of chlorine isotope fractionation in acid systems and applications to volcanic fumaroles. Geochimica et Cosmochimica Acta 74 264-273. doi:10.1016/j.gca.2009.09.032

Z.D. Sharp, C.K. Shearer, K.D. McKeegan, J.D. Barnes and Y.Q. Wang. The Chlorine Isotope Composition of the Moon and Implications for an Anhydrous Mantle. Science 329 1050-1053. doi:10.1126/science.1192606

S. Slaten, K.A. Fields, S. Santos, A. Barton, H.V. Rectanus & M. Bhargava. Integrated environmental forensics approach for evaluating the extent of dissolved perchlorate originating from multiple sources. Environmental Forensics 11 72-93. doi:10.1080/15275920903530124

R.L. Stotler, S.K. Frape & O Shouakar-Stash. An isotopic survey of ­81Br and ­37Cl of dissolved halides in the Canadian and Fennoscandian shields. Chemical Geology 274 38-55. doi:10.1016/j.chemgeo.2010.03.014


Y. Abe, R. Aravena, J. Zopfi, O. Shouakar-Stash, E. Cox, J.D. Roberts & D. Hunkeler. Carbon and Chlorine Isotope Fractionation during Aerobic Oxidation and Reductive Dechlorination of Vinyl Chloride and cis-1,2-Dichloroethene. Environmental Science and Technology 43 101-107. doi:10.1021/es801759k

J.D. Barnes, H. Paulick, Z.D. Sharp, W. Bach & G. Beaudoin. Stable isotope (­18O, ­D, ­37Cl) evidence for multiple fluid histories in mid-Atlantic abyssal peridotites (ODP Leg 209) Lithos 110 83-94. doi:10.1016/j.lithos.2008.12.004

J.D. Barnes, Z.D. Sharp, T.P. Fisher, D.R. Hilton, M.J. Carr. Chlorine isotope variations along the Central American volcanic front and back arc. Geochemsitry Geophysics Geosystems 10 Article number Q11S17. doi:10.1029/2009GC002587

J.K. Bohlke, P.B. Hatzonger, N.C. Sturchio, B.H. Gu, I Abbene & S.J. Mroczkowski. Atacama Perchlorate as an Agricultural Contaminant in Groundwater: Isotopic and Chronologic Evidence from Long Island, New York. Environmental Science and Technology 43 5619-5625. doi:10.1021/es9006433

H.G.M. Eggenkamp & M.L. Coleman. The effect of aqueous diffusion on the fractionation of chlorine and bromine stable isotopes. Geochimica et Cosmochimica Acta 73 3539-3548. doi:10.1016/j.gca.2009.03.036

J. Garcia-Veigas, L. Rossell, I. Zak, E. Playa, C. Ayora & A. Starinsky. Evidence of potash salt formation in the Pliocene Seldom Lagoon (Dead Sea rift, Israel). Chemical Geology 265 499-511. doi:10.1016/j.chemgeo.2009.05.013

S.A. Gleeson & M.P. Smith. The sources and evolution of mineralising fluids in iron oxide-copper-gold systems, Norbotten, Sweden: Constraints from Br/Cl ratios and stable Cl isotopes of fluid inclusion leachates. Geochimica et Cosmochimica Acta 73 5658-5672. doi:10.1016/j.gca.2009.06.005

S. Halas & A. Pelc. New isotope ratio mass spectrometric method for precise ­37Cl determinations. Rapid communications in Mass Spectrometry 23 1061-1064. doi:10.1002/rcm.3970

P.B. Hatzinger, J.K. Bohlke, N.C. Sturchio, B.H. Gu, L.J. Heraty & R.C. Borden. Fractionation of stable isotopes in perchlorate and nitrate during in situ biodegradation in a sandy aquifer. Environmental Chemistry 6 44-52. doi:10.1071/EN09008

D. Hunkeler, B.M. van Breukelen & M. Elsner. Modeling chlorine isotope trends during sequential transformation of chlorinated ethenes. Environmental Science and Technology 43 6750-6756. doi:10.1021/es900579z

G.D. Layne, A.J.R.Kent & W. Bach. ­37Cl systematics of a backarc spreading system: the Lau Basin. Geology 37 427-430.

T. Nahnibida, S.A. Gleeson, B.G. Rusk & L.I. Wassenaar. Cl/Br ratios and stable chlorine isotope analysis of magmatic-hydrothermal fluid inclusions from Butte, Montana and Bingham Canyon, Utah. Mineralium Deposita 44 837-848. doi:10.1007/s00126-009-0248-0

F. Partey, S. Lev, R. Casey, E. Widom, V.W. Lueth & J. Rakovan. Source of fluorine and petrogenesis of the Rio Grande risft-type barite-fluorite-galena deposits. Economic Geology 104 505-520. doi:10.2113/gsecongeo.104.4.505

O. Shouakar-Stash, S.K. Frape, R. Aravena, A. Gargini, M. Pasini & R.J. Drimmie. Analysis of compound specific chlorine stable isotopes of vinyl chloride by continuous flow-isotope ratio mass spectrometry (FC-IRMS). Environmental Forensics 10 299-306. doi:10.1080/15275920903347628

M. Stiller, J.M. Rosenbaum & A. Nishri. The origin of brines underlying Lake Kinneret. Chemical Geology 262 293-309. doi:10.1016/j.chemgeo.2009.01.030

HB Tan, MZ Ma, XY Mang, JX Xu & YK Xiao. Fractionation of chlorine isotope in salt mineral sequences and application: Research on sedimentary stage of ancient salt rock deposit in Tarim Basin and Western Qaidam Basin. Acta Petrologica Sinica 25 955-962 (in Chinese with English abstract).


M. Ader, S. Chaudehuri, J.D. Coates & M.L. Coleman. Microbial perchlorate reduction: A precise laboratory determination of the chlorine isotope fractionation and its possible biochemical basis. Earth and Planetary Science Letters 269 604-612. doi:10.1016/j.epsl.2008.03.023

H.M. Bao, J.D. Barnes, Z.D. Sharp & D.R. Marchant. Two chloride sources in soils of the McMurdo Dry Valleys, Antarctica. Journal of Geophysical Research - Atmospheres 113 Article number D03301. doi:10.1029/2007JD008703

J.D. Barnes, Z.D. Sharp & T.P. Fischer. Chlorine isotope variations across the Izu-Bonin-Mariana arc. Geology 36 883-886. doi:10.1130/G25182A.1

M. Bonifacie, V. Busigny, C. Mevel, P. Philippot, P. Agrinier, N. Jendrzejewski, M. Scambelluri & M. Javoy. Chlorine isotope composition in seafloor serpentinite and high-pressure metaperidotites. Insights into oceanic serpentinization and subduction processes. Geochimica et Cosmochimica Acta 72 126-139. doi:10.1016/j.gca.2007.10.010

M. Bonifacie, N. Jendrzejewski, P. Agrinier, E. Humler, M. Coleman & M. Javoy. The chlorine isotope composition of Earth's mantle. Science 319 1518-1520. doi:10.1126/science.1150988

M. Elsner &  D. Hunkeler. Evaluating chlorine isotope effects from isotope ratios and mass spectra of polychlorinated molecules. Analytical Chemistry 80 4731-4740. doi:10.1021/ac702543y

J. Fietzke, M. Frische, T.H. Hansteen & A. Eisenhauer. A simplified procedure for the determination of stable chlorine isotope ratios (­37Cl) using LA-MC-ICP-MS. Journal of Analytical Atomic Spectrometry 23 769-772. doi:10.1039/b718597a

C.Q. Liu, Y.C. Lang, H. Satake, J.H. Wu & S.L. Li. Identification of anthropogenic and natural inputs of sulphate and chloiride into the karstic ground water of Guiyang, SW China: Combined ­37Cl and ­34S approach. Environmental Science and Technology 42 5421-5427. doi:10.1021/es800380w

M. Mandalakis, H. Holmstrand, P. Andersson & O. Gustafsson. Compound-specific chlorine isotope analysis of polychlorinated biphenyls isolated from Aroclor and Clophen technical mixtures. Chemosphere 71 299-305. doi:10.1016/j.chemosphere.2007.09.004

M. Musashi, T. Oi, H.G.M. Eggenkamp & M. Matsuo. Chlorine isotope fractionation associated with volcanic activity at the Kusatsu-Bandaiko hot spring in Japan. Isotopes in Environmental and Health Studies 44 305-313. doi:10.1080/10256010802310051

A. Pelc & S. Halas. Negative ion source for chlorine isotope ratio measurements. Rapic Communications in Mass Spectrometry 22 3977-3982. doi:10.1002/rcm.3814

Z.D. Sharp & J.D. Barnes. Comment to " Chlorine stable isotopes and halogen concentrations in convergent margins with implications for the Cl isotopes cycle in the ocean" by Wei et al. A review of the Cl isotope composition of serpentinites and the global chlorine cycle. Earth and Planetary Science Letters 274 531-534. doi:10.1016/j.epsl.2008.07.031

A.L. Seyfferth, N.C. Sturchio & D.R. Parker. Is Perchlorate Metabolized or Re-Translocated within Lettuce Leaves? A Stable-Isotope Approach. Environmental Science and Technology 42 9437-9442. doi:10.1021/es802006e

W. Wei, M. Karstner & A. Spivack. Chlorine stable isotopes and halogen concentrations in convergent margins with implications for the Cl isotopes cycle in the ocean. Earth and Planetary Science Letters 266 90-104. doi:10.1016/j.epsl.2007.11.009

W. Wei, M. Karsnter & A. Spivack. Reply to comment on: "Chlorine stable isotopes and halogen concentrations in convergent margins with implications for the Cl isotopes cycles in the ocean. Earth and Planetary Science Letters 274 535. doi:10.1016/j.epsl.2008.07.023


S.V. Alexeev, L.P. Alexeeva, V.N. Borisov, O. Shouakar-Stash, S.K. Frape, F. Chabaux & A.M. Kononov. Isotopic composition (H, O, Cl, Sr) of ground brines of the Siberian Platform. Russion Geology and Geophysics 48 225-236. doi:10.1016/j.rgg.2007.02.011

W.K. Annable, S.K. Frape, O. Shouakar-Stash, T. Shanoff, R.J. Drimmie & F.E. Harvey. Cl-37, N-15, C-13 isotopic analysis of common agro-chemicals for identifying non-point source agricultural contaminants. Applied Geochemistry 22 1530-1536. doi:0.1016/j.apgeochem.2007.03.049

M. Bonifacie, N. Jendrzejewski, P. Agrinier, M. Coleman, F. Pineau & M. Javoy. Pyrohydrolysis-IRMS determination of silicate chlorine stable isotope compositions. Application to oceanic crust and meteorite samples. Chemical Geology 242 187-201. doi:10.1016/j.chemgeo.2007.03.012

M. Bonifacie, C. Monnin, N. Jendrzejewski, P. Agrinier & M. Javoy. Chlorine stable isotopic composition of basement fluids of the eastern flank of the Juan de Fuca ridge (ODP leg 168). Earth and Planetary Science Letters 260 10-22. doi:10.1016/j.epsl.2007.05.011

I.C. Bourg & G. Sposito. Molecular dynamics simulations of kinetic isotope fractionation during the diffusion of ionic species in liquid water. Geochimica et Cosmochimica Acta 71 5583-5589. doi:10.1016/j.gca.2007.01.021

C.J. Eastoe, T.M. Peryt, O.Y. Petrychenko & D. Geisler-Cussey. Stable chlorine isotopes in Phanerozoic evaporites. Applied Geochemsitry 22 575-588. doi:10.1016/j.apgeochem.2006.12.012

T.B. Hofstetter, C.M. Reddy, L.J. Heraty, M. Berg & N.C. Sturchio. Carbon and chlorine isotope effects during abiotic reductive dechlorination of polychlorinated ethanes. Environmental Science and Technology 41 4662-4668. doi:10.1021/es0704028

H. Holmstrand, M. Mandalakis, Z. Zencak, P. Andersson & O. Gustafsson. First compound-specific chlorine-isotope analysis of environmentally-bioaccumulated organochlorines indicates a degradation-relatable kinetic isotope effect for DDT. Chemosphere 69  1533-1539. doi:10.1016/j.chemosphere.2007.05.067

M. Musashi, T. Oi, H.G.M. Eggenkamp, Y. Yato & M. Matsuo. Anion-exchange chromatographic study of the chlorine isotope effect accompanying hydration. Journal of Chromatography A 1140 121-125. doi:10.1016/j.chroma.2006.11.051

R.P. Philp. The emergence of stable isotopes in environmental and forensic geochemsitry studies: a review. Environmental Chemistry Letters 5 57-66. doi:10.1007/s10311-006-0081-y

K. Sakaguchi-Soder, J. Jager, H. Grund, F Matthaus & C. Schuth. Monitoring and evaluation of dechlorination processes using compound-specific chlorine isotope analysis. Rapid Communications in Mass Spectrometry 21 3077-3084. doi:10.1002/rcm.3170

Z.D. Sharp, J.D. Barnes, A.J. Brearly, M. Chaussidon, T.P. Fisher & V.S. Kamenetsky. Chlorine isotope homogeneity of the mantle, crust and carbonaceous chondrites. Nature 446 1062-1065. doi:10.1038/nature05748

O. Shouakar-Stash, S.V. Alexeev, S.K. Frape, L.P. Alexeeva & R.J. Drimmie. Geochemsitry and stable isotopic signatures, including chlorine and bromine isotopes, of the deep groundwaters of the Siberian Platform, Russia. Applied Geochemistry 22 589-605. doi:10.1016/j.apgeochem.2006.12.005

N.C. Sturchio, J.K. Bohlke, A.D. Beloso, S.H. Streger, L.J. Heraty & P.B. Hatzinger. Oxygen and chlorine isotopic fractionation during perchlorate biodegradation: Laboratory results and implications for forensics and natural attenuation studies. Environmental Science and Technology 41 2796-2802. doi:10.1021/es0621849

S.P. Sylva, L. Ball, R.K. Nelson & C.M. Reddy. Compound-specific 81Br/79Br analysis by capillary gas chromatography/multicollector inductively coupled plasma mass spectrometry. Rapid Communications in Mass Spectrometry 21 3301-3305. doi:10.1002/rcm.3211

Y.K. Xiao, X.F. Wang, H.Z. Wei, H.L. Li & Z.Q. Zhao. A new method for the removal fo SO42- for isotopic measurement of chlorine. Chemical Geology 238 38-43. doi:10.1016/j.chemgeo.2006.10.011

M. Zhang, S.K. Frape, A.J. Love, A.L. Herczeg, B.E. Lehmann, U. Beyerle & R. Purtschert. Chlorine stable isotope studies of old grounbwater, southwestern Great Artesian Basin, Australia. Applied Geochemsitry 22 557-574. doi:10.1016/j.apgeochem.2006.12.004

A.M. Zyakun, Y.E. Firsova, M.L. Torgonskaya, N.V. Doronina & Y.A. Trotsenko. Changes of chlorine isotope composition characterize bacterial dehalogenation of dichloromethane. Applied Biochemistry and Microbiology 43 593-597. doi:10.1134/S000368380706004X


J.D. Barnes, J. Selverstone & Z.D. Sharp. Chlorine isotpe chemistry of serpentinites from Elba, Italy, as an indicator of fluid source and subsequent tectonic history. Geochemsitry Geophysics Geosystems 7 Article number Q08015. doi:10.1029/2006GC001296

J.D. Barnes & Z.D. Sharp. A chlorine isotope study of DSDP/ODP serpentinized ultramafic rocks: Insights into the serpentinization proces. Chemical Geology 228 246-265. doi:10.1016/j.chemgeo.2005.10.011

H.C. Chao & C.F. You. Distribution of B, Cl and their isotopes in pore waters separated from gas hydrate potential areas, offshore southwestern Taiwan. Terrestrial Atmospheric and Ocean Sciences 17 961-979. Abstract

M. Chiaradia, D. Banks, R. Cliff, R. Marschik & A. de Haller. Origin of fluids in iron oxide-copper-gold deposits: Constraints from ­37Cl, 87Sr/86Sr(i) and Cl/Br. Mineralium Deposita 41 565-573. doi:10.1007/s00126-006-0082-6

M.G. Dube, G.A. Benoy & L.I. Wassenaar. Contrasting pathways of assimilation: Stable isotope assesment of fish exposure to pulp mill effluents. Journal of Environmental Quality 35 1884-1893. doi:10.2134/jeq2005.0122

R. Hesse, P.K. Egeberg & S.K. Frape. Chlorine stable isotope ratios as tracer for pore-water advection rates in a submarine gas-hydrate field: Implication for hydrate concentration. Geofluids 6 1-7. doi:10.1111/j.1468-8123.2006.00123.x

H. Holmstrand, D. Gadomski, M. Mandalakis, M. Tysklind, R. Irvine, P. Andersson & O Gustafsson. Origin of PCDDs in ball clay assesed with compound-specific chlorine isotope analysis and radiocarbon dating. Environmental Science and Technology 40 3730-3735. doi:10.1021/es0602142

H. Holmstrand, M. Mandalakis, Z. Zencak, O. Gustafsson & P. Andersson. Chlorine isotope fractionation of a semi-volatile organochlorine compound during preparative megabore-column capillary gas chromatography.Journal of Chromatography A 1103 133-138. doi:10.1016/j.chroma.2005.11.009

S. Jalili & M. Akhavan. The study of isotope effects of chloroform and chloromethane using vibrational frequences. Journal of Molecular Structure - Theochem 765 105-114. doi:10.1016/j.theochem.2006.03.011

J.M. Marques, M. Andrade, P.M. Carreira, H.G.M. Eggenkamp, R.C. Graša, L. Airos-Barres & M. Antunes da Silva. Chemical and isotopic signatures of Na/HCO3/CO2-rich geofluids, North Portugal. Geofluids 6 273-287. doi:10.1111/j.1468-8123.2006.00144.x

F.M. Richter, R.A. Mendybaev, J.N. Christensen, I.D. Hutcheon, R.W. Williams, N.C. Sturchio & A.D. Beloso. Kinetic isotopic fractionation during diffusion of ionic species in water. Geochimica et Cosmochimica Acta 70 277-289. doi:10.1016/j.gca.2005.09.016

O. Shouakar-Stash, R.J, Drimmie, M. Zhang & S.K. Frape. Compound-specific chlorine isotope ratios of TCE, PCE and DCE isomeers by direct injection using CF-IRMS. Applied Geochemistry 21 766-781. doi:10.1016/j.apgeochem.2006.02.006

P.V. Shirodkar, Y.K. Xiao, A. Sarkar, S.G. Dalal & A.R. Chivas. Influence of air-sea fluxes on chlorine isotopic composition of ocean water: Implications for constancy in ­37Cl - A statistical inference. Environmental International 32 235-239. doi:10.1016/j.envint.2005.08.017

H.B. Tan, H.Z. Ma, H.Z. Wei, J.X. Xu & T.W. Li. Chlorine, sulfur and oxygen isotopic constraints on ancient evaporite deposit in the Western Tarim Basin, China. Geochemical Journal 40 569-577. Abstract

M.R.M.D. van Acker, A. Shahar, E.D. Young & M.L. Coleman. GC/Multicollector-ICPMS method for chlorine stable isotope analysis of chlorinated aliphatic hydrocarbons. Analytical Chemistry 78 4663-4667. doi:10.1021/ac0602120

J.H. Wu & H. Satake. Purification of CH3Cl from CH3I using cold trap with sealed 2,2,4-trimethylpentane for ­37Cl measurement. Analytica Chimica Acta 555 41-46. doi:10.1016/j.aca.2005.08.057

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Hans Eggenkamp 2012